Bis(2-benzamidobenzimidazolato-κ2 N 1,O)(N,N-dimethylformamide-κO)copper(II)
نویسندگان
چکیده
In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido-benzimidazolate anions and one O-coordinated dimethyl-formamide (DMF) mol-ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, with the DMF O atom at the apical site. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds result in chains of mol-ecules propagating along [100].
منابع مشابه
Bis(N,N-dimethylformamide-κO)bis(2,4,6-trinitrophenolato-κ2 O 1,O 2)copper(II)
The mol-ecule of the title complex, [Cu(C(6)H(2)N(3)O(7))(2)(C(3)H(7)NO)(2)], is disposed about a crystallographic centre of symmetry. The Cu(II) cation is six-coordinated by two phenolate O atoms and two ortho-nitro O atoms of two picrate units and by two carbonyl O atoms from two coordinated dimethyl-formamide mol-ecules, forming a distorted octa-hedral geometry.
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